CHARACTERIZATION OF A PEARLESCENT BIAXIALLY ORIENTED MULTILAYER POLYPROPYLENE FILM. PART 1
Abstract and keywords
Abstract (English):
The morphology, composition and properties of a commercial pearlescent and multilayer BOPP film were determined in the present study. The film was polypropylene and it was biaxially oriented as shown by FTIR spectroscopy and X-ray diffraction. FTIR spectroscopy indicated carbonate ions, EDX analysis indicated the presence of Ca element, X-ray diffraction showed the presence of calcite. The 30 µm film consisted of a core layer filled with calcite and 4 µm thick upper and lower layers without any filler and from different polymers. There were long air cavities in the core layer with aspect ratios of 23 and 19 in machine and transverse directions making the film pearlescent. The surfaces of the film were very smooth and had surface roughness in the range of 3.052 nm and 11.261 nm as determined by AFM. The film melted at 163.6 oC, had 51 % crystallinity and had 6.3 nm polymer crystals when heated at 10 oC/min rate.

Keywords:
pearlescent film, BOPP, x-ray diffraction, SEM, AFM, перламутровая пленка, БОПП, рентгеноструктурный анализ, СЭМ, АСМ
References

1. Nie H.Y, Walzak M. J., McIntyre N. S., Atomic force Microscope Study of Biaxially Oriented Films, Journal of Materials Engineering and Performance,2009, 13 (4) 4511-460.

2. Introduction of BOPP Film http://decrobopp.wordpress.com (2013).

3. Longo C., Savaris M., Zeni M., Brandalise R. N., Grisa A.M.C., Degradation Study of Polypropylene and Bioriented Polyproylene in the Environment. Materials Research, 2011, 14 (4) 442-48.

4. Raukula J. I., A New Technology to Manufacture Polypropylene Foam Sheet and Biaxially Oriented Foam Film; Thesis, Technical Research Centre of Finland (1998).

5. Ulku S., Balkose D., Arkis E.,Sipahioglu, M., A study of chemical and physical changes during biaxially oriented polypropylene film production, Journal of Polymer Engineering, 2003, 23, 437-456,

6. Kalapat N. and Amornsakchai T., Surface modification of biaxially oriented poly-propylene (BOPP) film using acrylic acid-corona treatment: Part I. Properties and characterization of treated films, Surface and Coating Technology,2012, 207, 594-601.

7. Nago, S. and Mizutani, Y., Microporous Polypropylene Sheets Containing CaCO3 Filler: Effects of Stretching Ratio and Removing CaCO3 Filler Journal of Applied Polymer Science, 1998, 68, 1543-1553

8. Opaque polymeric films and processes making the sameUS patent 6183856B1,2001

9. Koleske JV, Paint and Coating Testing Manual, 14th ed., the Gardner-Sward Ed., Philadelphia, PA: ASTM, 1995.

10. http://www.plastemart.com/upload/literature/246_art_bopp_in_foodpack.asp (2014).

11. Biswas J., Kim H., Lee B.H., Choe S., Air-hole properties of calcite-filled polypropylene copolymer films. 2008 Journal of Applied Polymer Science, 109, 1420-1430

12. Nie H.-Y, Walzak M.J., McIntyre N.S. Atomic Force Microscopy Study of Biaxially-Oriented Polypropylene Films JMEPEG, 2004, 13,451-460

13. Nie H.-Y. , Walzak M.J., McIntyre N.S. Draw-ratio-dependent morphology of biaxially oriented polypropylene films as determined by atomic force microscopy Polymer, 2000, 41, 2213-2218

14. Izer A., Kahyaoglu T. N., Balkose D., Valcium Soap Lubricants, Scince Journal of Volgograd State University, 10, 1, 16-25

15. Chen J., Xiang L, Controllable synthesis of calcium carbonate polymorphs at different temperatures, Powder Technology, 2009, 189, 64 - 69

16. Diez, F. J., Alvarino, C., Lopez, J., Ramirez, C. Abad, M. J., Cano, J., Garcia-Garabal, S. and Barral, L., “Influence of the Stretching in the Crystallinity of Biaxially Oriented Polypropylene (BOPP) Films,” Journal of Thermal Analysis and Calorimetry, 2005, 81, pp. 21-25.

17. Data from JCPDS Card Index File, Card 5-5868

18. Yang W., Li Z-M., Xie B.-H., Feng J-M., Shi W., Yang M-B. Stress-Induced Crystallization of Biaxially Oriented Polypropylene Journal of Applied Polymer Science, 2003, 89, 686-690

19. Bu H.S., Cheng S.Z.D., Wunderlich B. Addendum to the thermal properties of polypropylene. Die Makromolekulare Chemie Rapid Communications 1988,89(2), 75-77

20. Yamada K., Hikosaka M., Toda A., Yamazaki S., Tagashira K. Equilibrium melting temperature of isotactic polypropylene with high tacticity: 1. Determination by differential scanning calorimetry Macromolecules, 2003,36,4790-4801

21. http://en.wikipedia.org/wiki/Polypropylene

22. http://www.surface-tension.de/solid-surface-energy.htm

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