A relationship between the parameters of the reactivity of the monomers and the electron density on b-carbon double bond, as assessed by appropriate chemical shift of the protons in 1H NMR spectra. Based on the detected correlation obtained according to the equation, allowing for a wide range of vinyl monomers having electron-donating substituents on the double bond to the experimental studies to evaluate the parameters of their reactivity under the action of TiCl 4. Established correlations between the parameters of the reactivity of the monomers (such as growth rate constant circuit, the activation energy and enthalpy of polymerization), and the electron density on b-carbon double bond, as assessed by appropriate chemical shift of the protons in 1H NMR spectra can be used to further to select the optimum conditions for obtaining petroleum resins in the petrochemical industry.
катионная полимеризация, стирол, винилтолуол, инден, a-метилстирол, дициклопентадиен, тетрахлорид титана, термометрический метод, кинетика, химический сдвиг, корреляционные зависимости, cationic polymerization, styrene, vinyltoluene, indene, a-methylstyrene, dicyclopentadiene, titanium tetrachloride, thermometric method, the kinetics, chemical shift, correlations
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